These samples were processed in the same manner as real samples. The quantification limits, measured as average blanks plus six standard deviations of the average blanks) were 10–50 pg g−1 d.w.−1 for organochlorine compounds and 80–220 pg g−1 d.w.−1 for PAHs. Recoveries of individual compounds were in the 75–105% range, while relative standard deviations varied from 9 to 25% of average recoveries (triplicate analyses). Analyses of certified reference sediment material (IAEA-383) were

AZD6244 concentration routinely included in each batch of samples to monitor procedural accuracy. The low accuracy of naphthalene, acenapthene and acenaphthylene mean that these analytes were excluded from the list of the PAHs studied. The following PAHs were measured: Fluorene (FLN), Phenanthrene (PHE), Anthracene (ANT), Fluoranthene (FLT), Pyrene (PYR), Benzo(a)anthracene (BAA), Chrysene (CHR), B(b+k)fluoranthene (BKF), Benzo(a)pyrene (BAP), Dibenzo(a,h)anthracene (DBA), Benzo(ghi)perylene (BP) and Indeno(1,2,3-c,d)pyrene (IND). The PCBs included CB 28, CB 52, CB 101, CB 118, CB 138, CB 153 and CB 180. Individual component measurement uncertainty was calculated from 5 replicate analyses of compounds in certified reference material. The measurement uncertainties ranged from 10.75% (CB 180) to 23.26% (CB28) for individual PCBs and from 7.43% see more (FLT) to 27.27% (DBA) for individual PAHs. Seafloor sediment dynamics modulate contaminant accumulation on continental shelves. The historical

reconstruction of contaminant supplies to the western Barents Sea was obtained by converting sediment depth to time using 210Pb derived sedimentation velocities (Zaborska

et al. 2008). This enabled an average age to be assigned Carnitine palmitoyltransferase II to the individual sediment depth intervals in each core. The temporal pattern of POPs preserved in these sediment layers should reflect the dual influences of varied contaminant supplies over time and post-depositional sedimentary reworking and mineralization. Sediment mixing through physical and/or biological mechanisms was observed at three of the four stations sampled in this investigation (Table 1). Sediment disturbance was most pronounced at station VIII. This station is located in the Kvitøya Trench, which serves as a conduit of material to the central Arctic Basin (Vandieken et al. 2006, Carroll et al. 2008b). At both southern stations (I and IV), sediment mixing is pronounced in the upper 2 cm. This depth interval corresponds to a time period of approximately 40–60 years. The profile of organic contaminant concentrations with depth at station III provides an accurate historical record owing to the negligible influence of sediment mixing at this location. PAH concentrations (Σ12 PAH) measured in surface sediments ranged from 35 ± 18 ng g−1 d.w−1 to 132 ± 66 ng g−1 d.w−1 (Table 2). Surface sediment concentrations were lowest at northern stations – 35 ng g−1 d.w−1 (III) and 51 ng g−1 d.w−1 (VIII) – compared to southern stations – 132 ng g−1 d.w−1 (I) and 103 ng g−1 d.